Ruijie ZHANG
,
Lei LI
,
Zhongwei CHEN
,
Zhi HE
,
Wanqi JIE
材料科学技术（英）
The Levenberg-Marquardt method, the best algorithm to obtain the least-square solution of nonlinear equations, is applied to calculate the stable phase equilibria. It can get the best combination between robustness and speed of the calculations. Its application to ternary Al-Si-Mg system is executed in detail. The calculated phase equilibria agree well with the experimental results. Furthermore, the Levenberg-Marquardt method is not sensitive to the initial values.
关键词:
Levenberg-Marquardt method
,
null
,
null
Yongqin CHANG
,
Wanqi JIE
,
Xiping GUO
,
Fuyi CHEN
,
Weijun AN
材料科学技术（英）
MnxCd(1-x)In2Te4 (x=0.1) ingot was successfully grown by the modified Bridgman technique, which applied the accelerated crucible rotation technique (ACRT) in Bridgman process, or briefly ACRT-B. The growth interface profile shape and the composition distribution in the MnxCd(1-x)In2Te4 (x=0.1) ingot were analyzed. Even though the stoichiometric composition was synthesized in the original ingot, the composition has been redistributed during the ACRT-B growth process. Mn and Cd contents decrease while In increases along the longitudinal axis. The partition ratios of solutes Mn, Cd and In at the growth interface are evaluated by a mathematical method based on the experimental data, which are found to be 1.286, 1.926 and 0.729 in α phase growth process, and 1.120, 1.055 and 0.985 in β phase growth process, respectively. In the radial direction, Mn and Cd contents increase while In decreases with the distance from the centerline of the ingot.
关键词:
MnxCd(1-x)In2Te4
,
null
,
null
,
null
Wuxiao WANG
,
Bailing JIANG
,
Sen YUAN
,
Wanqi JIE
材料科学技术（英）
The liquid quenching method was adopted to study the solidification morphology and microstructure of AZ91D Mg alloy in semisolid. The results indicate that cooling rate has important effects upon the solidification structures. Under the cooling rate of liquid quenching, primary α-phase grows first by attaching on the original α grains, or independent nucleation and growth. The high cooling rate makes primary α-phase grow in "rags" or dendrite shape. Eutectic solidification is carried out in terms of both dissociated growth and symbiotic growth. The dissociated growth forms rough and large β-phase at grain boundaries, while symbiotic growth forms eutectic of laminar structure. The small liquid pool inside the original α-phase solidifies basically in the same way as that of intergranular liquid, but owing to less amount of liquid phase, the eutectic solidification is mainly carried out in the dissociated pattern.
关键词:
Magnesium alloy
,
液淬
,
凝固方式
,
凝固组织
Ruijie ZHANG
,
Zhi HE
,
Zhongwei CHEN
,
Wanqi JIE
材料科学技术（英）
A method to predict the solid-liquid interface stability during unidirectional solidification is developed by coupling M-S model with CALPHAD method. The method was applied to Al-0.38 Zn and Al-0.34 Si-0.14 Mg (wt pct) alloys, and the predicted results were compared with some former experimental data of the two alloys. The good agreement between the calculation results and the experimental data demonstrates the superiority of the present method to the classical one based on constant parameter assumptions.
关键词:
Interface stability
,
null
,
null
